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Studies on the autoxidation of fatty materials have revealed the\nfacts that the primary products of autoxidation are the peroxide or hydroperoxide (PV),\nand that by the transformation or decomposition of the peroxide and the interaction of\nthe peroxide with other materials of autoxidation and further oxidation of the peroxide,\nthe secondary products may be formed, including various aldehydes, ketons and acids\netc., some of which are responsible for rancid flavour and ordor. However, there has\nbeen probably little experimental evidence about the mechanism by which the lower\nproducts are formed.\nAnd then, in order to obtain some information on the process of the formation of\nlower carbonyl compounds by the oxidation, a preliminary experiment was carried out in\nconsidering the relationship between the formation of water-soluble carbonyl compounds\n(SC) and the quantity of the peroxide and between the formation of water-soluble\nand non-water-soluble carbonyl compounds (NC), adopting the oxidative action of\nsoybean lipoxidase for linoleic acid.", "subitem_description_type": "Other"}, {"subitem_description": "The formation of SC by the enzymatic oxidation of linoleic acid could hardly be\nperceived under the presence of smaller quantity of PV, while that of TC was appreciable\nin the same case. The addition of NC fraction to the mixture resulted in the acceleration\nof SC-formation and the inhibition of PV-formation. By some variations of the substrate\nconcentration, the rate of PV-formation was considerably affected, while that of SC\nwas hardly affected. 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On the Process of the Formation of Lower Carbonyl Compounds in the Enzymatic Oxidation of Linoleic Acid
http://hdl.handle.net/10232/13460
http://hdl.handle.net/10232/13460a261a614-0712-41a5-be36-12ab64d7d637
名前 / ファイル | ライセンス | アクション |
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AN00040498_v8_p52-55.pdf (2.3 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-05-08 | |||||
タイトル | ||||||
タイトル | On the Process of the Formation of Lower Carbonyl Compounds in the Enzymatic Oxidation of Linoleic Acid | |||||
別言語のタイトル | ||||||
その他のタイトル | リノール酸の酵素的酸化における低級カルボニル体の生成過程 | |||||
著者 |
OTA, Fuyuo
× OTA, Fuyuo |
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別言語の著者 | ||||||
姓名 | 太田, 冬雄 | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
要約(Abstract) | ||||||
内容記述タイプ | Other | |||||
内容記述 | In the previous report, it was confirmed that most of volatile carbonyl compounds found in fish flesh during storage was produced by the atmospheric oxidation of lipid fraction in the flesh. Studies on the autoxidation of fatty materials have revealed the facts that the primary products of autoxidation are the peroxide or hydroperoxide (PV), and that by the transformation or decomposition of the peroxide and the interaction of the peroxide with other materials of autoxidation and further oxidation of the peroxide, the secondary products may be formed, including various aldehydes, ketons and acids etc., some of which are responsible for rancid flavour and ordor. However, there has been probably little experimental evidence about the mechanism by which the lower products are formed. And then, in order to obtain some information on the process of the formation of lower carbonyl compounds by the oxidation, a preliminary experiment was carried out in considering the relationship between the formation of water-soluble carbonyl compounds (SC) and the quantity of the peroxide and between the formation of water-soluble and non-water-soluble carbonyl compounds (NC), adopting the oxidative action of soybean lipoxidase for linoleic acid. |
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要約(Abstract) | ||||||
内容記述タイプ | Other | |||||
内容記述 | The formation of SC by the enzymatic oxidation of linoleic acid could hardly be perceived under the presence of smaller quantity of PV, while that of TC was appreciable in the same case. The addition of NC fraction to the mixture resulted in the acceleration of SC-formation and the inhibition of PV-formation. By some variations of the substrate concentration, the rate of PV-formation was considerably affected, while that of SC was hardly affected. Thus, SC produced by the oxidation of linoleic acid, was supposed to be a later product derived from NC consequent on the formation of PV. |
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収録雑誌名 |
鹿児島大学水産学部紀要=Memoirs of Faculty of Fisheries Kagoshima University 巻 8, p. 52-55 |
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作成日 | ||||||
日付 | 1960-02-20 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
ISSN | 0453087X | |||||
NII書誌ID(雑誌) | ||||||
収録物識別子タイプ | NCID | |||||
NC ID | AN00040498 | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
NDC | ||||||
主題Scheme | NDC | |||||
主題 | 660 | |||||
公開者・出版者 | ||||||
出版者 | 鹿児島大学 | |||||
公開者よみ | ||||||
公開者よみ | カゴシマ ダイガク | |||||
公開者別名 | ||||||
公開者別名 | Kagoshima University |