{"created":"2023-07-25T08:11:21.642054+00:00","id":11540,"links":{},"metadata":{"_buckets":{"deposit":"b6fe4ae3-9054-40ad-a8ca-0f54093c1cdd"},"_deposit":{"created_by":18,"id":"11540","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"11540"},"status":"published"},"_oai":{"id":"oai:ir.kagoshima-u.ac.jp:00011540","sets":["54:92"]},"author_link":["115794","115795","115796","115797"],"item_6_biblio_info_5":{"attribute_name":"収録雑誌名","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"271","bibliographicPageStart":"259","bibliographicVolumeNumber":"32","bibliographic_titles":[{"bibliographic_title":"Journal of carbohydrate chemistry","bibliographic_titleLang":"en"}]}]},"item_6_date_6":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2013-06-27","subitem_date_issued_type":"Issued"}]},"item_6_description_4":{"attribute_name":"要約(Abstract)","attribute_value_mlt":[{"subitem_description":"The self-assembling properties of the 6-O- and 6′-O-alkylsucrose mixtures with different chain lengths including octyl, decyl, dodecyl, and tetradecyl under aqueous conditions were studied and compared with those of the 6-O- and 6′-O-hexadecylsucrose mixture previously reported. The title compounds were synthesized from sucrose in five steps. The results of scanning and transmission electron microscopes, powder X-ray diffraction, and dynamic light scattering measurements indicated that the self-assembling properties of octyl, decyl, and dodecyl derivatives were completely different from those of the 6-O- and 6′-O-hexadecylsucrose mixture. The three derivatives reported here primarily formed lamellar planes, which further induced the formation of vesicle-type particles under aqueous conditions, whereas the previous derivatives primarily formed spherical micelles in water, which further assembled according to face-centered cubic organization by a drying process from the aqueous dispersion. It was also found that the 6-O- and 6′-O-tetradecylsucrose mixture showed concentration-induced micelle-lamellar transition behavior in an aqueous dispersion. Furthermore, the mixing of a regioisomer, 6′-O-hexadecylsucrose, with 6-O-hexadecylsucrose induced different self-assembling properties from that of 6-O-hexadecylsucrose alone, but this effect did not appear in the self-assembling of the 6-O- and 6′-O-octylsucrose mixture.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_6_publisher_23":{"attribute_name":"公開者・出版者","attribute_value_mlt":[{"subitem_publisher":"Taylor & Francis","subitem_publisher_language":"en"}]},"item_6_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1080/07328303.2013.809094","subitem_relation_type_select":"DOI"}}]},"item_6_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Taylor & Francis","subitem_rights_language":"en"}]},"item_6_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"07328303","subitem_source_identifier_type":"PISSN"}]},"item_6_source_id_9":{"attribute_name":"NII書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AA10628643","subitem_source_identifier_type":"NCID"}]},"item_6_subject_15":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"570","subitem_subject_scheme":"NDC"}]},"item_6_text_44":{"attribute_name":"備考","attribute_value_mlt":[{"subitem_text_value":"This is an Author's Accepted Manuscript of an article published in the Journal of Carbohydrate Chemistry, Vol. 32, Iss. 4, 2013, ©Taylor & Francis, available online at: http://www.tandfonline.com/10.1080/07328303.2013.809094."}]},"item_6_version_type_14":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Tanaka, Kouhei","creatorNameLang":"en"},{"creatorName":"タナカ, コウヘイ","creatorNameLang":"ja-Kana"},{"creatorName":"田中, 康平","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"115794","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Ohkawabata, Sachie","creatorNameLang":"en"},{"creatorName":"オオカワバタ, サチエ","creatorNameLang":"ja-Kana"},{"creatorName":"大川畑, 幸恵","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"115795","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Yamamoto, Kazuya","creatorNameLang":"en"},{"creatorName":"ヤマモト, カズヤ","creatorNameLang":"ja-Kana"},{"creatorName":"山元, 和哉","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"115796","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Kadokawa, Jun-Ichi","creatorNameLang":"en"},{"creatorName":"カドカワ, ジュンイチ","creatorNameLang":"ja-Kana"},{"creatorName":"門川, 淳一","creatorNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"115797","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-31"}],"displaytype":"detail","filename":"0732-8303_v32n4_p259-271.pdf","filesize":[{"value":"787.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"0732-8303_v32n4_p259-271.pdf","objectType":"fulltext","url":"https://ir.kagoshima-u.ac.jp/record/11540/files/0732-8303_v32n4_p259-271.pdf"},"version_id":"8ec93e77-8029-4c26-8d62-0ec6c47f4244"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Sucrose","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Monoalkyl ether","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Self-assembly","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Micelle","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Lamellar","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Self-Assembling Properties of 6-O- and 6′-O-Alkylsucrose Mixtures Having Different Chain Lengths Under Aqueous Conditions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Self-Assembling Properties of 6-O- and 6′-O-Alkylsucrose Mixtures Having Different Chain Lengths Under Aqueous Conditions","subitem_title_language":"en"}]},"item_type_id":"6","owner":"18","path":["92"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-07-24"},"publish_date":"2014-07-24","publish_status":"0","recid":"11540","relation_version_is_last":true,"title":["Self-Assembling Properties of 6-O- and 6′-O-Alkylsucrose Mixtures Having Different Chain Lengths Under Aqueous Conditions"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-02-07T07:25:40.402074+00:00"}