@article{oai:ir.kagoshima-u.ac.jp:00002090, author = {隈元, 実忠 and KUMAMOTO, Sanetada and 染川, 賢一 and SOMEKAWA, Kenichi and 井手, 俊輔 and IDE, Shunsuke and 井手, 宏子 and IDE, Hiroko}, journal = {鹿児島大学工学部研究報告, The research reports of the Faculty of Engineering, Kagoshima University}, month = {Sep}, note = {Photo-irradiation of hexachloro-2, 4-cyclohexadienone (I), hexachloro-2, 5-cyclohexadienone (II), octachloro-3-cyclohexenone (III) or octachloro-2-cyclohexenone (IV) with tetrachloroethylene mainly gave a same product, decachlorophenetole (V, mp. 173.5-174°C). It was thought that the reaction was initiated by photo-decomposition of I, II, III or IV to give intermediates of pentachlorophenoxy and pentachloroethyl radicals. V was converted to several products by a few treatments. One of these is a treatment of V with zinc powder to give pentachlorophenyl trichlorovinyl ether (mp. 71-72°C). Meanwhile, as a IR peak of 2140 cm^{-1} was obserbed when I or II in tetrachloroethylene was irradiated by a high pressure mercury lamp, we studied about this peak.}, pages = {53--57}, title = {ポリクロル-シクロヘキサ-エノンおよび-ジェノンとテトラクロルエチレンとの光化学反応}, volume = {16}, year = {1974} }