{"created":"2023-07-25T08:04:01.126896+00:00","id":2090,"links":{},"metadata":{"_buckets":{"deposit":"19dd75eb-53c8-41a4-8b4a-5def80010f33"},"_deposit":{"created_by":18,"id":"2090","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"2090"},"status":"published"},"_oai":{"id":"oai:ir.kagoshima-u.ac.jp:00002090","sets":["228:273:5336","35:36"]},"author_link":[],"item_7_biblio_info_5":{"attribute_name":"収録雑誌名","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1974-09","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"57","bibliographicPageStart":"53","bibliographicVolumeNumber":"16","bibliographic_titles":[{"bibliographic_title":"鹿児島大学工学部研究報告","bibliographic_titleLang":"ja"},{"bibliographic_title":"The research reports of the Faculty of Engineering, Kagoshima University","bibliographic_titleLang":"en"}]}]},"item_7_date_6":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"1974-09","subitem_date_issued_type":"Issued"}]},"item_7_description_4":{"attribute_name":"要約(Abstract)","attribute_value_mlt":[{"subitem_description":"Photo-irradiation of hexachloro-2, 4-cyclohexadienone (I), hexachloro-2, 5-cyclohexadienone (II), octachloro-3-cyclohexenone (III) or octachloro-2-cyclohexenone (IV) with tetrachloroethylene mainly gave a same product, decachlorophenetole (V, mp. 173.5-174°C). It was thought that the reaction was initiated by photo-decomposition of I, II, III or IV to give intermediates of pentachlorophenoxy and pentachloroethyl radicals. V was converted to several products by a few treatments. One of these is a treatment of V with zinc powder to give pentachlorophenyl trichlorovinyl ether (mp. 71-72°C). Meanwhile, as a IR peak of 2140 cm^{-1} was obserbed when I or II in tetrachloroethylene was irradiated by a high pressure mercury lamp, we studied about this peak.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_7_publisher_23":{"attribute_name":"公開者・出版者","attribute_value_mlt":[{"subitem_publisher":"鹿児島大学","subitem_publisher_language":"ja"},{"subitem_publisher":"Kagoshima University","subitem_publisher_language":"en"}]},"item_7_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0451212X","subitem_source_identifier_type":"PISSN"}]},"item_7_source_id_9":{"attribute_name":"NII書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00040363","subitem_source_identifier_type":"NCID"}]},"item_7_subject_15":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_7_version_type_14":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"隈元, 実忠","creatorNameLang":"ja"},{"creatorName":"KUMAMOTO, Sanetada","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"染川, 賢一","creatorNameLang":"ja"},{"creatorName":"SOMEKAWA, Kenichi","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"井手, 俊輔","creatorNameLang":"ja"},{"creatorName":"IDE, Shunsuke","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"井手, 宏子","creatorNameLang":"ja"},{"creatorName":"IDE, Hiroko","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-27"}],"displaytype":"detail","filename":"AN00040363_v16_p53-57.pdf","filesize":[{"value":"9.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"AN00040363_v16_p53-57.pdf","objectType":"fulltext","url":"https://ir.kagoshima-u.ac.jp/record/2090/files/AN00040363_v16_p53-57.pdf"},"version_id":"7be9dfd7-4fbb-4f98-b466-33662c9c35df"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ポリクロル-シクロヘキサ-エノンおよび-ジェノンとテトラクロルエチレンとの光化学反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ポリクロル-シクロヘキサ-エノンおよび-ジェノンとテトラクロルエチレンとの光化学反応","subitem_title_language":"ja"},{"subitem_title":"THE PHOTOREACTION OF POLYCHLORO-CYCLOHEXA-ENONES OR -DIENONES WITH TETRACHLOROETHYLENE","subitem_title_language":"en"}]},"item_type_id":"7","owner":"18","path":["36","5336"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2015-06-18"},"publish_date":"2015-06-18","publish_status":"0","recid":"2090","relation_version_is_last":true,"title":["ポリクロル-シクロヘキサ-エノンおよび-ジェノンとテトラクロルエチレンとの光化学反応"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-02-20T04:57:04.554869+00:00"}