@article{oai:ir.kagoshima-u.ac.jp:00002167,
 author = {上村, 芳三 and UEMURA, Yoshimitsu and 幡手, 泰雄 and HATATE, Yasuo and 碇, 醇 and IKARI, Atsushi},
 journal = {鹿児島大学工学部研究報告, The research reports of the Faculty of Engineering, Kagoshima University},
 month = {Nov},
 note = {Supported metal catalyst are widely used in automotive, petrochemical, and chemical industries. Impregnation, consisting of (1) soaking, (2) drying, and (3) activation steps, is a major process to manufacture such catalysts. Previously, we showed that the drying conditions of impregnated supports affect the intraparticle distribution of active ingredient and the overall activity of the hydrogenation of cyclohexene with the nickel-alumina catalysts. Information about the intrinsic kinetics and the physical properties of the catalysts enables us to discuss the overall activity of those. In this paper, the intrinsic kinetics of the hydrogenation of cyclohexene with a nickel-alumina catalyst previously used are investigated using crushed catalyst. The results are as follows: (1) Althogh the rate is proportional to the linear velocity of the reactant gas, no mass transfer controlling can be approximated. (2) The rate is proportional to the partial pressure of cyclohexene and has a positive dependence on the partial pressure of hydrogen. (3) The apparent activation energy of the rate is 93 kJ/mol.},
 pages = {201--207},
 title = {ニッケル/アルミナ触媒によるシクロヘキセン気相接触水素化反応の速度論的研究},
 volume = {27},
 year = {1985}
}