{"created":"2023-07-25T08:06:45.805650+00:00","id":5653,"links":{},"metadata":{"_buckets":{"deposit":"a73d0e1f-c4a4-4240-ae55-bb5aaac0f7bb"},"_deposit":{"created_by":18,"id":"5653","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"5653"},"status":"published"},"_oai":{"id":"oai:ir.kagoshima-u.ac.jp:00005653","sets":["54:92"]},"author_link":["122888","122889","122890","122891"],"item_6_biblio_info_5":{"attribute_name":"収録雑誌名","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1990","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"588","bibliographicPageStart":"585","bibliographicVolumeNumber":"6","bibliographic_titles":[{"bibliographic_title":"Analytical sciences","bibliographic_titleLang":"en"}]}]},"item_6_date_6":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"1990-08-01","subitem_date_issued_type":"Issued"}]},"item_6_description_4":{"attribute_name":"要約(Abstract)","attribute_value_mlt":[{"subitem_description":"An ion selective electrode was prepared which exhibited selectivity for terephthalate over various interfering anions including phthalate under alkaline conditions; a dionium cation, decamethylenebis(trioctylphosphonium) (abbreviated as C,oBP), was used as the sensing material. Ion selective electrodes based on conventional monoonium cations such as \"Capriquat\" did not exhibit such selectivity. The butyl analogs of CnBPs were examined as ion-pair reagents in\nion-pair chromatography for phthalates. Under alkaline elution conditions, the base-line separation of three phthalate isomers (phthalate, isophthalate and terephthalate) was achieved. When monoonium reagents such as tetrabutylammonium were used, the retentions of these isomers considerably decreased, compared to the case of dionium reagents, and the separation could not be attained. The superiority of the dionium cations in both the sensing and separation systems was discussed.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_6_publisher_23":{"attribute_name":"公開者・出版者","attribute_value_mlt":[{"subitem_publisher":"公益社団法人日本分析化学会","subitem_publisher_language":"ja"}]},"item_6_relation_11":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.2116/analsci.6.585","subitem_relation_type_select":"DOI"}}]},"item_6_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09106340","subitem_source_identifier_type":"PISSN"}]},"item_6_subject_15":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"433","subitem_subject_scheme":"NDC"}]},"item_6_version_type_14":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ohki, Akira","creatorNameLang":"en"},{"creatorName":"オオキ, アキラ","creatorNameLang":"ja-Kana"},{"creatorName":"大木, 章","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamura, Masanobu","creatorNameLang":"en"},{"creatorName":"ヤムラ, マサノブ","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Takagi, Makoto","creatorNameLang":"en"},{"creatorName":"タカギ, マコト","creatorNameLang":"ja-Kana"},{"creatorName":"高木, 誠","creatorNameLang":"ja"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maeda, Shigeru","creatorNameLang":"en"},{"creatorName":"マエダ, シゲル","creatorNameLang":"ja-Kana"},{"creatorName":"前田, 滋","creatorNameLang":"ja"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-28"}],"displaytype":"detail","filename":"Dionium Cations as Novel Sensing and Separation Reagents for Phthalates in Ion-Selective Electrode Method and in Ion-Pair Chromatography.pdf","filesize":[{"value":"258.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"Dionium Cations as Novel Sensing and Separation Reagents for Phthalates in Ion-Selective Electrode Method and in Ion-Pair Chromatography.pdf","objectType":"fulltext","url":"https://ir.kagoshima-u.ac.jp/record/5653/files/Dionium Cations as Novel Sensing and Separation Reagents for Phthalates in Ion-Selective Electrode Method and in Ion-Pair Chromatography.pdf"},"version_id":"5365ffbb-03f7-4bdc-8009-943b52efc9c0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Dionium cation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ion selective electrode","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ion-pair chromatography","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"phthalate isomer dianions","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dionium Cations as Novel Sensing and Separation Reagents for Phthalates in Ion-Selective Electrode Method and in Ion-Pair Chromatography","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dionium Cations as Novel Sensing and Separation Reagents for Phthalates in Ion-Selective Electrode Method and in Ion-Pair Chromatography","subitem_title_language":"en"}]},"item_type_id":"6","owner":"18","path":["92"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-02-10"},"publish_date":"2014-02-10","publish_status":"0","recid":"5653","relation_version_is_last":true,"title":["Dionium Cations as Novel Sensing and Separation Reagents for Phthalates in Ion-Selective Electrode Method and in Ion-Pair Chromatography"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-02-07T07:13:09.727302+00:00"}