{"created":"2023-07-25T08:08:12.806300+00:00","id":7527,"links":{},"metadata":{"_buckets":{"deposit":"ec10dd9f-ba30-4245-bf24-2896b569e489"},"_deposit":{"created_by":18,"id":"7527","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"7527"},"status":"published"},"_oai":{"id":"oai:ir.kagoshima-u.ac.jp:00007527","sets":["228:273:5296","35:36"]},"author_link":[],"item_7_biblio_info_5":{"attribute_name":"収録雑誌名","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1961-09","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"109","bibliographicPageStart":"105","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"鹿児島大学工学部研究報告","bibliographic_titleLang":"ja"},{"bibliographic_title":"The research reports of the Faculty of Engineering, Kagoshima University","bibliographic_titleLang":"en"}]}]},"item_7_date_6":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"1961-09","subitem_date_issued_type":"Issued"}]},"item_7_description_4":{"attribute_name":"要約(Abstract)","attribute_value_mlt":[{"subitem_description":"Among perchlorinated phenols, those of the o-quinonoid type (3, 5-cyclohexadien-one-\n1) are rich in reactivity (cf. S. Kumamoto, Kogyo Kagaku Zasshi, 64, 181 (1961)). The reaction of 2, 2, 4, 6-tetrachloro-3, 5-dimethyl- (A) and 2, 2, 3, 4, 5, 6-hexachloro-3, 5-cyclohexadienone-1 (B) with pyridine bases were studied and obained the following results. (A) and (B) reacted with pyridine in chloroform solution to yield pyridinium chlorides (AP), (BP) involved 1 mol. water of crystallization respectively, which are easily soluble in water or alcohols. Treating (AP) and (BP) above with 28% NH_4OHaq. or NaOHaq. yellow crystals of pridinium hydroxide, (AP') and (BP') were obtained. And furthermore, it was found that (AP') and (BP') added conc. HCl to return to the original (AP) and (BP) respectively. Through the infrared spectra, these compounds were understood to be 2, 4, 6-trichloro-3, 5-dimethylphenoxy-pyridinium chloride (AP), -pytidinium hydroxide (AP') and 2, 3, 4, 5, 6-pentachloro-phenoxy-pyridinium chloride (BP), -pyridinium hydroxide (BP'). And in the reaction of other pyridine bases (α-, β-, γ-picoline and 2, 6-lutidine)　with (A) and (B), pure compounds were not obtained.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_7_publisher_23":{"attribute_name":"公開者・出版者","attribute_value_mlt":[{"subitem_publisher":"鹿児島大学","subitem_publisher_language":"ja"},{"subitem_publisher":"Kagoshima University","subitem_publisher_language":"en"}]},"item_7_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0451212X","subitem_source_identifier_type":"PISSN"}]},"item_7_source_id_9":{"attribute_name":"NII書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AN00040363","subitem_source_identifier_type":"NCID"}]},"item_7_subject_15":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"430","subitem_subject_scheme":"NDC"}]},"item_7_version_type_14":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"隈元, 実忠","creatorNameLang":"ja"},{"creatorName":"KUMAMOTO, Sanetada","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-28"}],"displaytype":"detail","filename":"AN00040363_v1_p105-109.pdf","filesize":[{"value":"11.3 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"AN00040363_v1_p105-109.pdf","objectType":"fulltext","url":"https://ir.kagoshima-u.ac.jp/record/7527/files/AN00040363_v1_p105-109.pdf"},"version_id":"d93aafac-ec40-4875-9e48-f0936d9872b3"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"o-キイノド型過塩素化フェノール類とピリジン塩基との反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"o-キイノド型過塩素化フェノール類とピリジン塩基との反応","subitem_title_language":"ja"},{"subitem_title":"REACTION OF PERCHLORINATED PHENOLS OF THE -QUINONOID TYPE WITH PYRIDINE BASES","subitem_title_language":"en"}]},"item_type_id":"7","owner":"18","path":["36","5296"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2011-02-14"},"publish_date":"2011-02-14","publish_status":"0","recid":"7527","relation_version_is_last":true,"title":["o-キイノド型過塩素化フェノール類とピリジン塩基との反応"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-02-20T05:01:10.135538+00:00"}