{"created":"2023-07-25T08:08:42.461544+00:00","id":8148,"links":{},"metadata":{"_buckets":{"deposit":"07e1f89b-8c40-4928-9518-2f2357d0397c"},"_deposit":{"created_by":18,"id":"8148","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"8148"},"status":"published"},"_oai":{"id":"oai:ir.kagoshima-u.ac.jp:00008148","sets":["41:76"]},"author_link":["39124"],"item_8_date_6":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2012-05-31","subitem_date_issued_type":"Issued"}]},"item_8_description_4":{"attribute_name":"要約(Abstract)","attribute_value_mlt":[{"subitem_description":"2010-2011年度科学研究費助成事業(科学研究費補助金(若手研究(B)))研究成果報告書　課題番号：22750007　研究代表者：須磨航介 (鹿児島大学教育学部准教授)","subitem_description_language":"ja","subitem_description_type":"Other"},{"subitem_description":"放電ノズルを組み合わせたCRD分光器の開発を行った。研究期間前半は東京大学、後半は鹿児島大学で装置を立ち上げた。CRDSではキャビティの反射率が分光器の感度に直接影響を与えるため、鹿児島大の装置では鹿児島地方特有の火山灰対策等などの特別な工夫が必要であったが、期間前半の東京大学の装置とほぼ同程度の性能の装置の開発が終了した。試料分子線の光軸外への拡散を防ぐため、スリットノズルに改良を加えた。HO_3ラジカルの高精度分子軌道計算を行った。回転定数の実験値と実験結果をよく再現するポテンシャルから求めた振動回転定数からHO_3の平衡構造を決定した。","subitem_description_language":"ja","subitem_description_type":"Other"},{"subitem_description":"The Cavity Ringdown (CRD) spectrometer combined with the discharged nozzle was constructed in the University of Tokyo and Kagoshima University. Because CRD spectrometer is severely affected by reflectivity of mirror, the apparatus in Kagoshima was installed in clean room to keep out the ash from the volcano. New type slit nozzle was installed in new spectrometer to prevent the sample gas from diverging outside the optical axis. High-level ab initio calculation of the HO_3 radical was performed by using MRCI. The obtained potential energy surface of HO_3 reproduces experimental results well. The equilibrium structure of the HO_3 radical was determined by using the vibration-rotation coupling constants, which was obtained from the potential energy surface.","subitem_description_language":"en","subitem_description_type":"Other"}]},"item_8_publisher_23":{"attribute_name":"公開者・出版者","attribute_value_mlt":[{"subitem_publisher":"鹿児島大学","subitem_publisher_language":"ja"},{"subitem_publisher":"Kagoshima University","subitem_publisher_language":"en"}]},"item_8_subject_15":{"attribute_name":"NDC","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_8_text_41":{"attribute_name":"科研費番号 ","attribute_value_mlt":[{"subitem_text_value":"22750007"}]},"item_8_version_type_14":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"須磨, 航介","creatorNameLang":"ja"},{"creatorName":"スマ, コウスケ","creatorNameLang":"ja-Kana"},{"creatorName":"SUMA, Kohsuke","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-10-28"}],"displaytype":"detail","filename":"22750007seika.pdf","filesize":[{"value":"414.1 kB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"label":"22750007seika.pdf","objectType":"fulltext","url":"https://ir.kagoshima-u.ac.jp/record/8148/files/22750007seika.pdf"},"version_id":"35f0c449-ca47-41d6-933b-120f98c6ac58"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ラジカル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ラジカル錯体","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"キャビティーリングダウン分光","subitem_subject_language":"ja","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"research report","resourceuri":"http://purl.org/coar/resource_type/c_18ws"}]},"item_title":"放電後混合型スリットノズルを組み合わせたCRDSによる新規不安定分子種の検出","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"放電後混合型スリットノズルを組み合わせたCRDSによる新規不安定分子種の検出","subitem_title_language":"ja"},{"subitem_title":"Detection of transient species by using Cavity Ringdown spectrometer combined with a new type slit nozzle","subitem_title_language":"en"}]},"item_type_id":"8","owner":"18","path":["76"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-12-22"},"publish_date":"2014-12-22","publish_status":"0","recid":"8148","relation_version_is_last":true,"title":["放電後混合型スリットノズルを組み合わせたCRDSによる新規不安定分子種の検出"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-03-07T08:43:02.877572+00:00"}