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Temperature-induced Chirality Reversal of Induced Circular Dichroism of Premicellar Aggregates of Acridine Orange Derivatives and Dodecanoyl-L-threonine in Aqueous Solution
http://hdl.handle.net/10232/266
http://hdl.handle.net/10232/266fd9e7fd2-b3a8-449b-a775-eb2e92dfc280
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
06-2CPS.pdf (688.6 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2013-12-18 | |||||
| タイトル | ||||||
| タイトル | Temperature-induced Chirality Reversal of Induced Circular Dichroism of Premicellar Aggregates of Acridine Orange Derivatives and Dodecanoyl-L-threonine in Aqueous Solution | |||||
| 言語 | en | |||||
| 著者 |
Hayakawa, Katumitu
× Hayakawa, Katumitu× Sato, Mayuko× Nagata, Izumi× Yamato, Naoya× Murata, Hiroshi× Tanokura, Masaru |
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| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Induced Circular Dichroism | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Acylamino acid | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Alkyacridine orange | |||||
| キーワード | ||||||
| 言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Absorption spectra | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 要約(Abstract) | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Circular dichroism (CD) and absorption spectra were measured for acridine orange derivatives: 3,6-bis(dimethylamino) acridine (AO), 3,6-bis(dimethylamino)-10-methylacridinium bromide (C1AO), and 3,6-bis(dimethylamino)-10-dodecylacridinium bromide (C12AO) in aqueous dodecanoyl-L-threonine (C12Thr) solutions at 30, 40, 50 and 60°C and pH 8-9. CD spectra were not induced for AO and C1AO in C12Thr aqueous solutions. Induced circular dichroism (ICD) based on the exciton interaction was found for premicellar aggregates of C12AO with C12Thr, but the micellar aggregates failed to induce circular dichroism for solubilized C12AO at a higher concentration than C12Thr critical micelle concentration. The maximum ICD intensity was observed for 1:1.2 aggregates of C12AO and C12Thr. The ICD spectrum indicated negative chirality at 30°C, but positive chirality at 50°C. The chirality transition occurred at 40~45°C. The slow change in both the absorption and ICD spectra is ascribed partly to the rearrangement of dye alignment and partly to the growth of the aggregate; the system reaches final phase separation after a few days. |
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| 言語 | en | |||||
| 収録雑誌名 |
en : Colloid and polymer science : official journal of the Kolloid-Gesellschaft 巻 284, 号 12, p. 1453-1458, 発行日 2006 |
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| 作成日 | ||||||
| 日付 | 2006-01-01 | |||||
| 日付タイプ | Issued | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 0303402X | |||||
| NII書誌ID（雑誌） | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00610426 | |||||
| DOI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | https://doi.org/10.1007/s00396-006-1491-x | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| NDC | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 431 | |||||
| NIIsubject | ||||||
| 言語 | ja | |||||
| 主題Scheme | Other | |||||
| 主題 | ナノテクノロジー | |||||
| NIIsubject | ||||||
| 言語 | ja | |||||
| 主題Scheme | Other | |||||
| 主題 | コロイド化学 | |||||
| 公開者・出版者 | ||||||
| 出版者 | Springer Verlag | |||||
| 言語 | en | |||||
