{"_buckets": {"deposit": "362c7450-53c1-424b-9373-eb0f53ad89de"}, "_deposit": {"created_by": 3, "id": "4683", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "4683"}, "status": "published"}, "_oai": {"id": "oai:ir.kagoshima-u.ac.jp:00004683", "sets": ["36", "5344"]}, "author_link": ["82167", "82169", "82168", "82170", "82172", "82171"], "item_7_alternative_title_18": {"attribute_name": "別言語のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "安息香酸から無水安息香酸の電解合成"}]}, "item_7_biblio_info_5": {"attribute_name": "収録雑誌名", "attribute_value_mlt": [{"bibliographicPageEnd": "159", "bibliographicPageStart": "153", "bibliographicVolumeNumber": "24", "bibliographic_titles": [{"bibliographic_title": "鹿児島大学工学部研究報告"}]}]}, "item_7_date_6": {"attribute_name": "作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "1982-10-04"}]}, "item_7_description_4": {"attribute_name": "要約(Abstract)", "attribute_value_mlt": [{"subitem_description": "Electrolysis of benzoic acid was investigated by means of controlled current operation in acetonitrile with platinum disk electrodes. Benzoic anhydride was obtained from an anolyte at 20-30% of current efficiency as one electron reaction. At the same time, acetamide and hydrogen perchlorate were obtained from the anolyte, and triethylamine was obtained from the catholyte. The yield of acetamide was nearly equal to benzoic anhydride. On the other hand, the yield of triethylamine approximately agreed with the sum of benzoic anhydride and hydrogen perchlorate. Addition of cyclohexene to the system caused to decrease the current efficiency of benzoic anhydride.\nFrom these results, reaction mechanism that is shown in equation (4) to (6) was considered the most reasonable to the formation of benzoic anhydride. The same electrolysis was applied to toluic acids and corresponding anhydrides were obtained at reasonable current efficiency.", "subitem_description_type": "Other"}]}, "item_7_full_name_2": {"attribute_name": "著者よみ", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "82169", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "タカハシ, タケシゲ"}]}, {"nameIdentifiers": [{"nameIdentifier": "82170", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "カマダ, ミツシ"}]}]}, "item_7_full_name_3": {"attribute_name": "別言語の著者", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "82171", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "高橋, 武重"}]}, {"nameIdentifiers": [{"nameIdentifier": "82172", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "鎌田, 三司"}]}]}, "item_7_publisher_23": {"attribute_name": "公開者・出版者", "attribute_value_mlt": [{"subitem_publisher": "鹿児島大学"}]}, "item_7_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0451212X", "subitem_source_identifier_type": "ISSN"}]}, "item_7_source_id_9": {"attribute_name": "NII書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00040363", "subitem_source_identifier_type": "NCID"}]}, "item_7_subject_15": {"attribute_name": "NDC", "attribute_value_mlt": [{"subitem_subject": "431", "subitem_subject_scheme": "NDC"}]}, "item_7_text_24": {"attribute_name": "公開者よみ", "attribute_value_mlt": [{"subitem_text_value": "カゴシマ ダイガク"}]}, "item_7_text_25": {"attribute_name": "公開者別名", "attribute_value_mlt": [{"subitem_text_value": "Kagoshima University"}]}, "item_7_text_30": {"attribute_name": "NIIタイプ", "attribute_value_mlt": [{"subitem_text_value": "Departmental Bulletin Paper"}]}, "item_7_version_type_14": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "TAKAHASHI, Takeshige"}], "nameIdentifiers": [{"nameIdentifier": "82167", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "KAMADA, Mitsushi"}], "nameIdentifiers": [{"nameIdentifier": "82168", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-10-28"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AN00040363_v24_p153-159.pdf", "filesize": [{"value": "730.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 730100.0, "url": {"label": "AN00040363_v24_p153-159.pdf", "url": "https://ir.kagoshima-u.ac.jp/record/4683/files/AN00040363_v24_p153-159.pdf"}, "version_id": "0b4afab1-54b7-45f5-9baa-6beb6affbf4b"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Electrolytic Synthesis of Benzoic Anhydride from Benzoic Acid", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Electrolytic Synthesis of Benzoic Anhydride from Benzoic Acid"}]}, "item_type_id": "7", "owner": "3", "path": ["36", "5344"], "permalink_uri": "http://hdl.handle.net/10232/12475", "pubdate": {"attribute_name": "公開日", "attribute_value": "2012-03-25"}, "publish_date": "2012-03-25", "publish_status": "0", "recid": "4683", "relation": {}, "relation_version_is_last": true, "title": ["Electrolytic Synthesis of Benzoic Anhydride from Benzoic Acid"], "weko_shared_id": 3}