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安息香酸から無水安息香酸の電解合成
http://hdl.handle.net/10232/12475
http://hdl.handle.net/10232/124757f368790-ae84-4f1b-87b0-51f6562af438
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
AN00040363_v24_p153-159.pdf (730.1 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||||||
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| 公開日 | 2012-03-25 | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | Electrolytic Synthesis of Benzoic Anhydride from Benzoic Acid | |||||||||||||
| タイトル言語 | en | |||||||||||||
| タイトル | ||||||||||||||
| タイトル | 安息香酸から無水安息香酸の電解合成 | |||||||||||||
| タイトル言語 | ja | |||||||||||||
| 著者 |
高橋, 武重
× 高橋, 武重
× 鎌田, 三司
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| 言語 | ||||||||||||||
| 言語 | eng | |||||||||||||
| 資源タイプ | ||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||
| 資源タイプ | departmental bulletin paper | |||||||||||||
| 要約 | ||||||||||||||
| 内容記述タイプ | Other | |||||||||||||
| 内容記述 | Electrolysis of benzoic acid was investigated by means of controlled current operation in acetonitrile with platinum disk electrodes. Benzoic anhydride was obtained from an anolyte at 20-30% of current efficiency as one electron reaction. At the same time, acetamide and hydrogen perchlorate were obtained from the anolyte, and triethylamine was obtained from the catholyte. The yield of acetamide was nearly equal to benzoic anhydride. On the other hand, the yield of triethylamine approximately agreed with the sum of benzoic anhydride and hydrogen perchlorate. Addition of cyclohexene to the system caused to decrease the current efficiency of benzoic anhydride. From these results, reaction mechanism that is shown in equation (4) to (6) was considered the most reasonable to the formation of benzoic anhydride. The same electrolysis was applied to toluic acids and corresponding anhydrides were obtained at reasonable current efficiency. |
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| 内容記述言語 | en | |||||||||||||
| 収録雑誌名 |
ja : 鹿児島大学工学部研究報告 en : The research reports of the Faculty of Engineering, Kagoshima University 巻 24, p. 153-159, 発行日 1982-10 |
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| 作成日 | ||||||||||||||
| 日付 | 1982-10 | |||||||||||||
| 日付タイプ | Issued | |||||||||||||
| ISSN | ||||||||||||||
| 収録物識別子タイプ | PISSN | |||||||||||||
| ISSN | 0451212X | |||||||||||||
| NII書誌ID（雑誌） | ||||||||||||||
| 収録物識別子タイプ | NCID | |||||||||||||
| NC ID | AN00040363 | |||||||||||||
| 出版タイプ | ||||||||||||||
| 出版タイプ | VoR | |||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||
| NDC | ||||||||||||||
| 主題Scheme | NDC | |||||||||||||
| 主題 | 431 | |||||||||||||
| 公開者・出版者 | ||||||||||||||
| 出版者 | 鹿児島大学 | |||||||||||||
| 出版者言語 | ja | |||||||||||||
| 公開者・出版者 | ||||||||||||||
| 出版者 | Kagoshima University | |||||||||||||
| 出版者言語 | en | |||||||||||||
