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Aggregate of Amphiphilic Block Copolymer as a Pseudo-Stationary Phase in Capillary Electrophoresis
http://hdl.handle.net/10232/20272
http://hdl.handle.net/10232/202727d74d464-fb3c-4421-b0d2-2d96bf21ddb9
名前 / ファイル | ライセンス | アクション |
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Aggregate of Amphiphilic Block Copolymer as a Pseudo-Stationary Phase in Capillary Electrophoresis.pdf (54.1 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-02-10 | |||||
タイトル | ||||||
タイトル | Aggregate of Amphiphilic Block Copolymer as a Pseudo-Stationary Phase in Capillary Electrophoresis | |||||
タイトル言語 | en | |||||
著者 |
中村, 透
× 中村, 透× 大木, 章× ミシロ, マサキ× 艶島, 修× 前田, 滋 |
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言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題言語 | en | |||||
主題Scheme | Other | |||||
主題 | Amphiphilic block copymer | |||||
キーワード | ||||||
主題言語 | en | |||||
主題Scheme | Other | |||||
主題 | aggregate | |||||
キーワード | ||||||
主題言語 | en | |||||
主題Scheme | Other | |||||
主題 | capillary electrophoresis | |||||
キーワード | ||||||
主題言語 | en | |||||
主題Scheme | Other | |||||
主題 | pseudo-stationary phase | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
要約 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The use of an aggregate of amphiphilic block copolymer 1, which consists of poly[(N-acetylimino)ethylene] and poly[(N-pentanoylimino)ethylene], for a pseudo-stationary phase in capillary electrophoresis has been examined. From gel-filtration chromatography, the aggregate from 1 (1-AG) was found to incorporate phenol. When the running solution contains 1-AG and sodium dodecyl sulfate (SDS), the electrophoretic mobility becomes nearly zero. Thus, it is found that when 1-AG and SDS are added to the running solution, SDS is incorporated in 1-AG, giving negative charges on the 1-AG, which works as a pseudo-stationary phase. By the addition of 1-AG and a low concentration of SDS in the running solution, six phenols are separated and the migration order of phenols is basically dependent on their lipophilicities. However, the migration order of some phenols is different from that in the micellar electrokinetic chromatography (MEKC) using a hig concentration SDS. | |||||
内容記述言語 | en | |||||
収録雑誌名 |
en : Analytical sciences 巻 15, 号 9, p. 879-883, 発行日 1999 |
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作成日 | ||||||
日付 | 1999-09-01 | |||||
日付タイプ | Issued | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
ISSN | 09106340 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
DOI | https://doi.org/10.2116/analsci.15.879 | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
NDC | ||||||
主題Scheme | NDC | |||||
主題 | 433 | |||||
公開者・出版者 | ||||||
出版者 | 公益社団法人日本分析化学会 | |||||
出版者言語 | ja |