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Molecular Orbital Calculations for Dioxetane as a Part of the Intermediate of Firefly Luciferin
http://hdl.handle.net/10232/451
http://hdl.handle.net/10232/451b2ab49b8-5b95-41b4-8f84-729d8bc81ce2
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2015-04-28 | |||||
タイトル | ||||||
タイトル | Molecular Orbital Calculations for Dioxetane as a Part of the Intermediate of Firefly Luciferin | |||||
著者 |
伊藤, 伸一
× 伊藤, 伸一× 行田, 尚義 |
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著者よみ | ||||||
姓名 | イトウ, シンイチ | |||||
著者よみ | ||||||
姓名 | ナメダ, ナオヨシ | |||||
別言語の著者 | ||||||
姓名 | ITOH, Shinichi | |||||
別言語の著者 | ||||||
姓名 | NAMEDA, Naoyoshi | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
要約(Abstract) | ||||||
内容記述タイプ | Other | |||||
内容記述 | Firefly luciferin (Ln) is an absorbing substance showing a high quantum efficiency of bioluminescence. Several proposals about the mechanism of the luminescence in this system have been explained by investigators. A dioxetane structure exists within the intermediate of Ln and plays an important role to occure the emission. In this report, we attempt to calculate the electronic structures of the dioxetane and to correlate the calculated results with the experimental observations as a first step to recognize the mechanism of the bioluminescence of Ln. The obtained results show that the 2p electrons of O and C are important as to the electronic excitations of the luminescence. The calculated excitation energy agrees with the observed value in spite of a simplified system. | |||||
収録雑誌名 |
鹿児島大学工学部研究報告 巻 38, p. 257-260 |
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作成日 | ||||||
日付 | 1996-09-30 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
ISSN | 0451212X | |||||
NII書誌ID(雑誌) | ||||||
収録物識別子タイプ | NCID | |||||
NC ID | AN00040363 | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
NDC | ||||||
主題Scheme | NDC | |||||
主題 | 500 | |||||
NIIsubject | ||||||
主題Scheme | Other | |||||
主題 | 工学 | |||||
公開者・出版者 | ||||||
出版者 | 鹿児島大学 | |||||
公開者よみ | ||||||
公開者よみ | カゴシマダイガク | |||||
公開者別名 | ||||||
公開者別名 | Kagoshima university |