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Self-Assembling Properties of 6-O- and 6′-O-Alkylsucrose Mixtures Having Different Chain Lengths Under Aqueous Conditions
http://hdl.handle.net/10232/20628
http://hdl.handle.net/10232/20628da01783d-644e-4fa3-9d13-0fb70e1205de
| 名前 / ファイル | ライセンス | アクション |
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0732-8303_v32n4_p259-271.pdf (787.1 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2014-07-24 | |||||
| タイトル | ||||||
| タイトル | Self-Assembling Properties of 6-O- and 6′-O-Alkylsucrose Mixtures Having Different Chain Lengths Under Aqueous Conditions | |||||
| タイトル言語 | en | |||||
| 著者 |
田中, 康平
× 田中, 康平× 大川畑, 幸恵× 山元, 和哉× 門川, 淳一 |
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| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Sucrose | |||||
| キーワード | ||||||
| 主題言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Monoalkyl ether | |||||
| キーワード | ||||||
| 主題言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Self-assembly | |||||
| キーワード | ||||||
| 主題言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Micelle | |||||
| キーワード | ||||||
| 主題言語 | en | |||||
| 主題Scheme | Other | |||||
| 主題 | Lamellar | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| 要約 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | The self-assembling properties of the 6-O- and 6′-O-alkylsucrose mixtures with different chain lengths including octyl, decyl, dodecyl, and tetradecyl under aqueous conditions were studied and compared with those of the 6-O- and 6′-O-hexadecylsucrose mixture previously reported. The title compounds were synthesized from sucrose in five steps. The results of scanning and transmission electron microscopes, powder X-ray diffraction, and dynamic light scattering measurements indicated that the self-assembling properties of octyl, decyl, and dodecyl derivatives were completely different from those of the 6-O- and 6′-O-hexadecylsucrose mixture. The three derivatives reported here primarily formed lamellar planes, which further induced the formation of vesicle-type particles under aqueous conditions, whereas the previous derivatives primarily formed spherical micelles in water, which further assembled according to face-centered cubic organization by a drying process from the aqueous dispersion. It was also found that the 6-O- and 6′-O-tetradecylsucrose mixture showed concentration-induced micelle-lamellar transition behavior in an aqueous dispersion. Furthermore, the mixing of a regioisomer, 6′-O-hexadecylsucrose, with 6-O-hexadecylsucrose induced different self-assembling properties from that of 6-O-hexadecylsucrose alone, but this effect did not appear in the self-assembling of the 6-O- and 6′-O-octylsucrose mixture. | |||||
| 内容記述言語 | en | |||||
| 収録雑誌名 |
en : Journal of carbohydrate chemistry 巻 32, 号 4, p. 259-271, 発行日 2013 |
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| 作成日 | ||||||
| 日付 | 2013-06-27 | |||||
| 日付タイプ | Issued | |||||
| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| ISSN | 07328303 | |||||
| NII書誌ID（雑誌） | ||||||
| 収録物識別子タイプ | NCID | |||||
| NC ID | AA10628643 | |||||
| DOI | ||||||
| 識別子タイプ | DOI | |||||
| DOI | https://doi.org/10.1080/07328303.2013.809094 | |||||
| 権利 | ||||||
| 権利情報の言語 | en | |||||
| 権利情報 | Taylor & Francis | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
| NDC | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 570 | |||||
| 公開者・出版者 | ||||||
| 出版者 | Taylor & Francis | |||||
| 出版者言語 | en | |||||
| 備考 | ||||||
| 備考 | This is an Author's Accepted Manuscript of an article published in the Journal of Carbohydrate Chemistry, Vol. 32, Iss. 4, 2013, ©Taylor & Francis, available online at: http://www.tandfonline.com/10.1080/07328303.2013.809094. | |||||
