{"_buckets": {"deposit": "1d19ea21-c08d-4e9e-8a12-2fabf0284979"}, "_deposit": {"created_by": 3, "id": "4554", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "4554"}, "status": "published"}, "_oai": {"id": "oai:ir.kagoshima-u.ac.jp:00004554", "sets": ["36", "5345"]}, "author_link": ["81700", "81702", "81701", "3495", "81699"], "item_7_alternative_title_19": {"attribute_name": "タイトルよみ", "attribute_value_mlt": [{"subitem_alternative_title": "ZSM-5 ゼオライト ノ ショクバイ カッセイ ニ オヨボス Si/Alヒ ノ エイキョウ"}]}, "item_7_biblio_info_5": {"attribute_name": "収録雑誌名", "attribute_value_mlt": [{"bibliographicPageEnd": "124", "bibliographicPageStart": "119", "bibliographicVolumeNumber": "26", "bibliographic_titles": [{"bibliographic_title": "鹿児島大学工学部研究報告"}]}]}, "item_7_date_6": {"attribute_name": "作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "1984-11-01"}]}, "item_7_description_4": {"attribute_name": "要約(Abstract)", "attribute_value_mlt": [{"subitem_description": "Three kinds of HZSM-5 zeolite with different Si/Al ratios were prepared to determine the effect of the Si/Al ratio on the catalytic activity of the zeolite. The Si/Al ratio did not affect on the surface area nor the crystallinity. However, the acidity of the zeolite decreased with an increasing ratio of Si/Al. The acid strength distribution of the zeolite was compared with those of amorphous silica-alumina and HY type zeolite. The results indicate that HZSM-5 has many strong acid sites which could be effective for the disproportionation of aromatic hydrocarbons. An o-xylene isomerization reaction was carried out for the HZSM-5 zeolites in a fixed type reactor. The catalytic activity of the zeolites was greater than that of amorphous silica-alumina, but no activity difference was observed among the different zeolites. Unlike the isomerization over silica-alumina catalyst, 1, 2, 4- and 1, 3, 5- trimethybenzenes could not be detected in the product streams. The result suggests that the micropore of the zeolite, composed  of a 10 membered oxygen rings, \nprevents a bulky compound such as trimethylbenzene from being produced.", "subitem_description_type": "Other"}]}, "item_7_full_name_2": {"attribute_name": "著者よみ", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "81700", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "タカハシ, タカシゲ"}]}]}, "item_7_full_name_3": {"attribute_name": "別言語の著者", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "81701", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "TAKAHASHI, Takashige"}]}, {"nameIdentifiers": [{"nameIdentifier": "81702", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "LIU, Xing Yun"}]}]}, "item_7_publisher_23": {"attribute_name": "公開者・出版者", "attribute_value_mlt": [{"subitem_publisher": "鹿児島大学"}]}, "item_7_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0451212X", "subitem_source_identifier_type": "ISSN"}]}, "item_7_source_id_9": {"attribute_name": "NII書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00040363", "subitem_source_identifier_type": "NCID"}]}, "item_7_subject_15": {"attribute_name": "NDC", "attribute_value_mlt": [{"subitem_subject": "573", "subitem_subject_scheme": "NDC"}]}, "item_7_text_24": {"attribute_name": "公開者よみ", "attribute_value_mlt": [{"subitem_text_value": "カゴシマ ダイガク"}]}, "item_7_text_25": {"attribute_name": "公開者別名", "attribute_value_mlt": [{"subitem_text_value": "Kagoshima University"}]}, "item_7_text_30": {"attribute_name": "NIIタイプ", "attribute_value_mlt": [{"subitem_text_value": "Departmental Bulletin Paper"}]}, "item_7_version_type_14": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "高橋, 武重"}], "nameIdentifiers": [{"nameIdentifier": "3495", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000020041543", "nameIdentifierScheme": "NRID", "nameIdentifierURI": " "}]}, {"creatorNames": [{"creatorName": "劉, 興允"}], "nameIdentifiers": [{"nameIdentifier": "81699", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-10-27"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AN00040363_v26_p119-124.pdf", "filesize": [{"value": "582.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 582300.0, "url": {"label": "AN00040363_v26_p119-124.pdf", "url": "https://ir.kagoshima-u.ac.jp/record/4554/files/AN00040363_v26_p119-124.pdf"}, "version_id": "02178db2-4112-45be-be69-b40a6ad75262"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "ZSM-5ゼオライトの触媒活性におよぼすSi/Al比の影響", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "ZSM-5ゼオライトの触媒活性におよぼすSi/Al比の影響"}, {"subitem_title": "Effect of Si/Al ratio on catalytic activioty of ZSM-5 zeolite", "subitem_title_language": "en"}]}, "item_type_id": "7", "owner": "3", "path": ["36", "5345"], "permalink_uri": "http://hdl.handle.net/10232/11241", "pubdate": {"attribute_name": "公開日", "attribute_value": "2015-06-09"}, "publish_date": "2015-06-09", "publish_status": "0", "recid": "4554", "relation": {}, "relation_version_is_last": true, "title": ["ZSM-5ゼオライトの触媒活性におよぼすSi/Al比の影響"], "weko_shared_id": 3}