ログイン
言語:

WEKO3

  • トップ
  • ランキング
To
lat lon distance
To

Field does not validate



インデックスリンク

インデックスツリー

メールアドレスを入力してください。

WEKO

One fine body…

WEKO

One fine body…

アイテム

{"_buckets": {"deposit": "e07dee5b-e99d-48b5-92e0-2a2cf3cacd7e"}, "_deposit": {"created_by": 3, "id": "653", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "653"}, "status": "published"}, "_oai": {"id": "oai:ir.kagoshima-u.ac.jp:00000653", "sets": ["36", "5296"]}, "author_link": ["79343", "79344", "79345"], "item_7_alternative_title_19": {"attribute_name": "タイトルよみ", "attribute_value_mlt": [{"subitem_alternative_title": "エンソカ フエノキノンガタ ブンシ カゴウブツ"}]}, "item_7_biblio_info_5": {"attribute_name": "収録雑誌名", "attribute_value_mlt": [{"bibliographicPageEnd": "104", "bibliographicPageStart": "97", "bibliographicVolumeNumber": "1", "bibliographic_titles": [{"bibliographic_title": "鹿児島大学工学部研究報告"}]}]}, "item_7_date_6": {"attribute_name": "作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "1961-09-05"}]}, "item_7_description_4": {"attribute_name": "要約(Abstract)", "attribute_value_mlt": [{"subitem_description": "Eight of chlorinated and methylated p-quinones and twelve of phenols and mainly chlorinated derivatives were prepared. Then combining these p-quinones (1 mol. respectively) with phenols (2 mols. respectively) and dissolving them in benzene, CCl_4, CHCl_3, CS_2 to be left for several days, along with the evaparation of solvent, crystals in beautiful color were yieded, several tens of molecular compounds (MC) being formed. Among p-quinones, tetramethyl-p-quinone was revealed easiest to form MC. On the other hand, the formation of MC were observed difficult as hydrogen atoms of the nucleus of p-quinone was substituted with too much chlorine atoms. Some of MC were acknowledged to have suddenly changed from each proper color to yellow at their respective discolouration temperature even below the melting point. This discolouration temperature is to be supposed as the temperature where the intermolecular hydrogen bond of \u003e C=O・・・H-O- is cut off and decomposed to individual constituents. The existence of intermolecular hydrogen bond in the crystalline state was acknowledged through the infrared spectra. After all, it was concluded that these crystals were nothing but molecular compounds of the analogous phenoquinone type formed by intermolecular hydrogen bond binding between p-quinones (1 mol.) and phenols (2 mols.).", "subitem_description_type": "Other"}]}, "item_7_full_name_2": {"attribute_name": "著者よみ", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "79344", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "クマモト, サネタダ"}]}]}, "item_7_full_name_3": {"attribute_name": "別言語の著者", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "79345", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "KUMAMOTO, Sanetada"}]}]}, "item_7_publisher_23": {"attribute_name": "公開者・出版者", "attribute_value_mlt": [{"subitem_publisher": "鹿児島大学"}]}, "item_7_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0451212X", "subitem_source_identifier_type": "ISSN"}]}, "item_7_source_id_9": {"attribute_name": "NII書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00040363", "subitem_source_identifier_type": "NCID"}]}, "item_7_subject_15": {"attribute_name": "NDC", "attribute_value_mlt": [{"subitem_subject": "430", "subitem_subject_scheme": "NDC"}]}, "item_7_text_24": {"attribute_name": "公開者よみ", "attribute_value_mlt": [{"subitem_text_value": "カゴシマ ダイガク"}]}, "item_7_text_25": {"attribute_name": "公開者別名", "attribute_value_mlt": [{"subitem_text_value": "Kagoshima University"}]}, "item_7_text_30": {"attribute_name": "NIIタイプ", "attribute_value_mlt": [{"subitem_text_value": "Departmental Bulletin Paper"}]}, "item_7_text_45": {"attribute_name": "備考(非公開)", "attribute_value_mlt": [{"subitem_text_value": "20230426_PDFカバーページを除いた本文ファイルに差替え"}]}, "item_7_version_type_14": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "隈元, 実忠"}], "nameIdentifiers": [{"nameIdentifier": "79343", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-10-27"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AN00040363_v1_p97-104.pdf", "filesize": [{"value": "19.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 19600000.0, "url": {"label": "AN00040363_v1_p97-104.pdf", "url": "https://ir.kagoshima-u.ac.jp/record/653/files/AN00040363_v1_p97-104.pdf"}, "version_id": "d452b61d-9343-4f95-af03-5668be2255e6"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "塩素化フエノキノン型分子化合物", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "塩素化フエノキノン型分子化合物"}, {"subitem_title": "MOLECULAR COMPOUNDS OF CHLORINATED PHENOQUINONE TYPE", "subitem_title_language": "en"}]}, "item_type_id": "7", "owner": "3", "path": ["36", "5296"], "permalink_uri": "http://hdl.handle.net/10232/10379", "pubdate": {"attribute_name": "公開日", "attribute_value": "2011-02-14"}, "publish_date": "2011-02-14", "publish_status": "0", "recid": "653", "relation": {}, "relation_version_is_last": true, "title": ["塩素化フエノキノン型分子化合物"], "weko_shared_id": 3}
  1. 掲載誌一覧
  2. 鹿児島大学工学部研究報告
  3. vol.1
  1. 工学部
  2. 工学部・紀要論文

塩素化フエノキノン型分子化合物

http://hdl.handle.net/10232/10379
http://hdl.handle.net/10232/10379
b53c542d-2a9a-4a8e-b53d-52642439fce8
名前 / ファイル ライセンス アクション
AN00040363_v1_p97-104.pdf AN00040363_v1_p97-104.pdf (19.6 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2011-02-14
タイトル
タイトル 塩素化フエノキノン型分子化合物
タイトル
タイトル言語 en
タイトル MOLECULAR COMPOUNDS OF CHLORINATED PHENOQUINONE TYPE
タイトルよみ
タイトルよみ エンソカ フエノキノンガタ ブンシ カゴウブツ
著者 隈元, 実忠

× 隈元, 実忠

WEKO 79343

隈元, 実忠

Search repository
著者よみ
姓名 クマモト, サネタダ
別言語の著者
姓名 KUMAMOTO, Sanetada
言語
言語 jpn
資源タイプ
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
資源タイプ departmental bulletin paper
要約(Abstract)
内容記述タイプ Other
内容記述 Eight of chlorinated and methylated p-quinones and twelve of phenols and mainly chlorinated derivatives were prepared. Then combining these p-quinones (1 mol. respectively) with phenols (2 mols. respectively) and dissolving them in benzene, CCl_4, CHCl_3, CS_2 to be left for several days, along with the evaparation of solvent, crystals in beautiful color were yieded, several tens of molecular compounds (MC) being formed. Among p-quinones, tetramethyl-p-quinone was revealed easiest to form MC. On the other hand, the formation of MC were observed difficult as hydrogen atoms of the nucleus of p-quinone was substituted with too much chlorine atoms. Some of MC were acknowledged to have suddenly changed from each proper color to yellow at their respective discolouration temperature even below the melting point. This discolouration temperature is to be supposed as the temperature where the intermolecular hydrogen bond of > C=O・・・H-O- is cut off and decomposed to individual constituents. The existence of intermolecular hydrogen bond in the crystalline state was acknowledged through the infrared spectra. After all, it was concluded that these crystals were nothing but molecular compounds of the analogous phenoquinone type formed by intermolecular hydrogen bond binding between p-quinones (1 mol.) and phenols (2 mols.).
収録雑誌名 鹿児島大学工学部研究報告

巻 1, p. 97-104
作成日
日付 1961-09-05
ISSN
収録物識別子タイプ ISSN
ISSN 0451212X
NII書誌ID(雑誌)
収録物識別子タイプ NCID
NC ID AN00040363
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
NDC
主題Scheme NDC
主題 430
公開者・出版者
出版者 鹿児島大学
公開者よみ
公開者よみ カゴシマ ダイガク
公開者別名
公開者別名 Kagoshima University
戻る
0
views
See details
Views

Versions

Ver.1 2023-07-25 09:53:27.326007
Show All versions

Share

Mendeley Twitter Facebook Print Addthis

Cite as

エクスポート

OAI-PMH
  • OAI-PMH JPCOAR
  • OAI-PMH DublinCore
  • OAI-PMH DDI
Other Formats
  • JSON
  • BIBTEX

Confirm


Powered by WEKO3


Powered by WEKO3