{"_buckets": {"deposit": "e07dee5b-e99d-48b5-92e0-2a2cf3cacd7e"}, "_deposit": {"created_by": 3, "id": "653", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "653"}, "status": "published"}, "_oai": {"id": "oai:ir.kagoshima-u.ac.jp:00000653", "sets": ["36", "5296"]}, "author_link": ["79343", "79344", "79345"], "item_7_alternative_title_19": {"attribute_name": "タイトルよみ", "attribute_value_mlt": [{"subitem_alternative_title": "エンソカ フエノキノンガタ ブンシ カゴウブツ"}]}, "item_7_biblio_info_5": {"attribute_name": "収録雑誌名", "attribute_value_mlt": [{"bibliographicPageEnd": "104", "bibliographicPageStart": "97", "bibliographicVolumeNumber": "1", "bibliographic_titles": [{"bibliographic_title": "鹿児島大学工学部研究報告"}]}]}, "item_7_date_6": {"attribute_name": "作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "1961-09-05"}]}, "item_7_description_4": {"attribute_name": "要約(Abstract)", "attribute_value_mlt": [{"subitem_description": "Eight of chlorinated and methylated p-quinones and twelve of phenols and mainly chlorinated derivatives were prepared. Then combining these p-quinones (1 mol. respectively) with phenols (2 mols. respectively) and dissolving them in benzene, CCl_4, CHCl_3, CS_2 to be left for several days, along with the evaparation of solvent, crystals in beautiful color were yieded, several tens of molecular compounds (MC) being formed. Among p-quinones, tetramethyl-p-quinone was revealed easiest to form MC. On the other hand, the formation of MC were observed difficult as hydrogen atoms of the nucleus of p-quinone was substituted with too much chlorine atoms. Some of MC were acknowledged to have suddenly changed from each proper color to yellow at their respective discolouration temperature even below the melting point. This discolouration temperature is to be supposed as the temperature where the intermolecular hydrogen bond of \u003e C=O・・・H-O- is cut off and decomposed to individual constituents. The existence of intermolecular hydrogen bond in the crystalline state was acknowledged through the infrared spectra. After all, it was concluded that these crystals were nothing but molecular compounds of the analogous phenoquinone type formed by intermolecular hydrogen bond binding between p-quinones (1 mol.) and phenols (2 mols.).", "subitem_description_type": "Other"}]}, "item_7_full_name_2": {"attribute_name": "著者よみ", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "79344", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "クマモト, サネタダ"}]}]}, "item_7_full_name_3": {"attribute_name": "別言語の著者", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "79345", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "KUMAMOTO, Sanetada"}]}]}, "item_7_publisher_23": {"attribute_name": "公開者・出版者", "attribute_value_mlt": [{"subitem_publisher": "鹿児島大学"}]}, "item_7_source_id_7": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "0451212X", "subitem_source_identifier_type": "ISSN"}]}, "item_7_source_id_9": {"attribute_name": "NII書誌ID", "attribute_value_mlt": [{"subitem_source_identifier": "AN00040363", "subitem_source_identifier_type": "NCID"}]}, "item_7_subject_15": {"attribute_name": "NDC", "attribute_value_mlt": [{"subitem_subject": "430", "subitem_subject_scheme": "NDC"}]}, "item_7_text_24": {"attribute_name": "公開者よみ", "attribute_value_mlt": [{"subitem_text_value": "カゴシマ ダイガク"}]}, "item_7_text_25": {"attribute_name": "公開者別名", "attribute_value_mlt": [{"subitem_text_value": "Kagoshima University"}]}, "item_7_text_30": {"attribute_name": "NIIタイプ", "attribute_value_mlt": [{"subitem_text_value": "Departmental Bulletin Paper"}]}, "item_7_text_45": {"attribute_name": "備考（非公開）", "attribute_value_mlt": [{"subitem_text_value": "20230426_PDFカバーページを除いた本文ファイルに差替え"}]}, "item_7_version_type_14": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "隈元, 実忠"}], "nameIdentifiers": [{"nameIdentifier": "79343", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-10-27"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "AN00040363_v1_p97-104.pdf", "filesize": [{"value": "19.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 19600000.0, "url": {"label": "AN00040363_v1_p97-104.pdf", "url": "https://ir.kagoshima-u.ac.jp/record/653/files/AN00040363_v1_p97-104.pdf"}, "version_id": "d452b61d-9343-4f95-af03-5668be2255e6"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "塩素化フエノキノン型分子化合物", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "塩素化フエノキノン型分子化合物"}, {"subitem_title": "MOLECULAR COMPOUNDS OF CHLORINATED PHENOQUINONE TYPE", "subitem_title_language": "en"}]}, "item_type_id": "7", "owner": "3", "path": ["36", "5296"], "permalink_uri": "http://hdl.handle.net/10232/10379", "pubdate": {"attribute_name": "公開日", "attribute_value": "2011-02-14"}, "publish_date": "2011-02-14", "publish_status": "0", "recid": "653", "relation": {}, "relation_version_is_last": true, "title": ["塩素化フエノキノン型分子化合物"], "weko_shared_id": 3}