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塩素化フエノキノン型分子化合物
http://hdl.handle.net/10232/10379
http://hdl.handle.net/10232/10379b53c542d-2a9a-4a8e-b53d-52642439fce8
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
AN00040363_v1_p97-104.pdf (19.6 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||
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| 公開日 | 2011-02-14 | |||||||||
| タイトル | ||||||||||
| タイトル | 塩素化フエノキノン型分子化合物 | |||||||||
| タイトル言語 | ja | |||||||||
| タイトル | ||||||||||
| タイトル | MOLECULAR COMPOUNDS OF CHLORINATED PHENOQUINONE TYPE | |||||||||
| タイトル言語 | en | |||||||||
| 著者 |
隈元, 実忠
× 隈元, 実忠
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| 言語 | ||||||||||
| 言語 | jpn | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | departmental bulletin paper | |||||||||
| 要約 | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | Eight of chlorinated and methylated p-quinones and twelve of phenols and mainly chlorinated derivatives were prepared. Then combining these p-quinones (1 mol. respectively) with phenols (2 mols. respectively) and dissolving them in benzene, CCl_4, CHCl_3, CS_2 to be left for several days, along with the evaparation of solvent, crystals in beautiful color were yieded, several tens of molecular compounds (MC) being formed. Among p-quinones, tetramethyl-p-quinone was revealed easiest to form MC. On the other hand, the formation of MC were observed difficult as hydrogen atoms of the nucleus of p-quinone was substituted with too much chlorine atoms. Some of MC were acknowledged to have suddenly changed from each proper color to yellow at their respective discolouration temperature even below the melting point. This discolouration temperature is to be supposed as the temperature where the intermolecular hydrogen bond of > C=O・・・H-O- is cut off and decomposed to individual constituents. The existence of intermolecular hydrogen bond in the crystalline state was acknowledged through the infrared spectra. After all, it was concluded that these crystals were nothing but molecular compounds of the analogous phenoquinone type formed by intermolecular hydrogen bond binding between p-quinones (1 mol.) and phenols (2 mols.). | |||||||||
| 内容記述言語 | en | |||||||||
| 収録雑誌名 |
ja : 鹿児島大学工学部研究報告 en : The research reports of the Faculty of Engineering, Kagoshima University 巻 1, p. 97-104, 発行日 1961-09 |
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| 作成日 | ||||||||||
| 日付 | 1961-09 | |||||||||
| 日付タイプ | Issued | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | PISSN | |||||||||
| ISSN | 0451212X | |||||||||
| NII書誌ID（雑誌） | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| NC ID | AN00040363 | |||||||||
| 出版タイプ | ||||||||||
| 出版タイプ | VoR | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
| NDC | ||||||||||
| 主題Scheme | NDC | |||||||||
| 主題 | 430 | |||||||||
| 公開者・出版者 | ||||||||||
| 出版者 | 鹿児島大学 | |||||||||
| 出版者言語 | ja | |||||||||
| 公開者・出版者 | ||||||||||
| 出版者 | Kagoshima University | |||||||||
| 出版者言語 | en | |||||||||
