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o-キイノド型過塩素化フェノール類とピリジン塩基との反応
http://hdl.handle.net/10232/10380
http://hdl.handle.net/10232/10380f657251e-98c9-405b-927e-4a387415e478
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
AN00040363_v1_p105-109.pdf (11.3 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||
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| 公開日 | 2011-02-14 | |||||||||
| タイトル | ||||||||||
| タイトル | o-キイノド型過塩素化フェノール類とピリジン塩基との反応 | |||||||||
| 言語 | ja | |||||||||
| タイトル | ||||||||||
| タイトル | REACTION OF PERCHLORINATED PHENOLS OF THE -QUINONOID TYPE WITH PYRIDINE BASES | |||||||||
| 言語 | en | |||||||||
| 著者 |
隈元, 実忠
× 隈元, 実忠
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| 言語 | ||||||||||
| 言語 | jpn | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | departmental bulletin paper | |||||||||
| 要約(Abstract) | ||||||||||
| 内容記述タイプ | Other | |||||||||
| 内容記述 | Among perchlorinated phenols, those of the o-quinonoid type (3, 5-cyclohexadien-one- 1) are rich in reactivity (cf. S. Kumamoto, Kogyo Kagaku Zasshi, 64, 181 (1961)). The reaction of 2, 2, 4, 6-tetrachloro-3, 5-dimethyl- (A) and 2, 2, 3, 4, 5, 6-hexachloro-3, 5-cyclohexadienone-1 (B) with pyridine bases were studied and obained the following results. (A) and (B) reacted with pyridine in chloroform solution to yield pyridinium chlorides (AP), (BP) involved 1 mol. water of crystallization respectively, which are easily soluble in water or alcohols. Treating (AP) and (BP) above with 28% NH_4OHaq. or NaOHaq. yellow crystals of pridinium hydroxide, (AP') and (BP') were obtained. And furthermore, it was found that (AP') and (BP') added conc. HCl to return to the original (AP) and (BP) respectively. Through the infrared spectra, these compounds were understood to be 2, 4, 6-trichloro-3, 5-dimethylphenoxy-pyridinium chloride (AP), -pytidinium hydroxide (AP') and 2, 3, 4, 5, 6-pentachloro-phenoxy-pyridinium chloride (BP), -pyridinium hydroxide (BP'). And in the reaction of other pyridine bases (α-, β-, γ-picoline and 2, 6-lutidine) with (A) and (B), pure compounds were not obtained. |
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| 言語 | en | |||||||||
| 収録雑誌名 |
ja : 鹿児島大学工学部研究報告 en : The research reports of the Faculty of Engineering, Kagoshima University 巻 1, p. 105-109, 発行日 1961-09 |
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| 作成日 | ||||||||||
| 日付 | 1961-09 | |||||||||
| 日付タイプ | Issued | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | PISSN | |||||||||
| 収録物識別子 | 0451212X | |||||||||
| NII書誌ID（雑誌） | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AN00040363 | |||||||||
| 出版タイプ | ||||||||||
| 出版タイプ | VoR | |||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
| NDC | ||||||||||
| 主題Scheme | NDC | |||||||||
| 主題 | 430 | |||||||||
| 公開者・出版者 | ||||||||||
| 出版者 | 鹿児島大学 | |||||||||
| 言語 | ja | |||||||||
| 公開者・出版者 | ||||||||||
| 出版者 | Kagoshima University | |||||||||
| 言語 | en | |||||||||
